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From Krebs to clinic: glutamine metabolism to cancer therapy | Nature Reviews Cancer

The rationale for injecting is bypassing first-pass metabolism, but that logic runs into a 14-minute plasma half-life and the fact that cells cannot import glutathione intact anyway

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To enhance neuronal GSH concentrations, several studies have evaluated the chelation of synaptically released zinc using a thiol-containing chemical compound, N-acetyl-cysteine (NAC)